Autor: |
Brovarets VS; Institute of Bioorganic Chemistry and Petrochemistry, National Academy of, Sciences of Ukraine, 1 Murmanska St., Kyiv 02660, Ukraine., Golovchenko OV; Institute of Bioorganic Chemistry and Petrochemistry, National Academy of, Sciences of Ukraine, 1 Murmanska St., Kyiv 02660, Ukraine., Rusanov EB; Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5, Murmanska St., Kyiv 02660, Ukraine., Rusanova JA; Department of Chemistry, Taras Shevchenko National University of Kyiv, 64/13, Volodymyrska Street, Kyiv 01601, Ukraine. |
Abstrakt: |
In the title phospho-rylated compound, C 20 H 26 Cl 3 N 2 O 6 P, the phthalimide unit is essentially planar (r.m.s. deviation = 0.0129 Å) and the O atoms of this unit deviate from the mean plane by 0.080 (3) and 0.041 (3) Å. In the crystal, pairs of mol-ecules are linked by N-H⋯O and weak C-H⋯O hydrogen bonds involving the same acceptor atom, forming inversion dimers. In addition, π-π stacking inter-actions between the phthalimide groups, with a centroid-centroid distance of 3.7736 (13) Å, and further weak C-H⋯O hydrogen bonds connect the inversion dimers into columns along [01]. |