Slow magnetic relaxation in a {Co II Co} complex containing a high magnetic anisotropy trigonal bipyramidal Co II centre.

Autor: Collet A; WestCHEM, School of Chemistry, University of Glasgow, University Avenue, Glasgow, G12 8QQ, UK. mark.murrie@glasgow.ac.uk., Craig GA, Heras Ojea MJ, Bhaskaran L, Wilson C, Hill S, Murrie M
Jazyk: angličtina
Zdroj: Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2018 Jul 17; Vol. 47 (28), pp. 9237-9240.
DOI: 10.1039/c8dt01997e
Abstrakt: We report a trinuclear mixed-valence {CoIICoIII2} complex, where the CoII centre adopts a trigonal bipyramidal geometry, leading to a large, easy-plane magnetic anisotropy and field-induced slow magnetic relaxation with a Raman-like relaxation process.
Databáze: MEDLINE