| Autor: |
Vazquez-Molina DA; Department of Chemistry, University of Central Florida, 4111 Libra Dr Orlando, FL 32816, USA. james.harper@ucf.edu fernando@ucf.edu., Pope GM, Ezazi AA, Mendoza-Cortes JL, Harper JK, Uribe-Romo FJ |
| Jazyk: |
angličtina |
| Zdroj: |
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2018 Jun 19; Vol. 54 (50), pp. 6947-6950. |
| DOI: |
10.1039/c8cc04292f |
| Abstrakt: |
We present a family of covalent organic frameworks that have been functionalized with oligo-(ethylene oxide) chains of varying lengths. Because of the open structure of the COFs, the side chains do not interfere with their crystallization obtaining materials with predictable crystal structure. The difference in length of the side-chains allowed for the determination of amphidynamic behaviour with the use of 13C solid-state NMR relaxation methods. Computational calculations further contribute to understanding the atomistic dynamic behaviour of the different atoms. This study demonstrates the ability to design complex behaviour in organic crystals. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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