| Autor: |
Nikolayenko VI; Department of Chemistry and Polymer Science, University of Stellenbosch, Matieland 7602, South Africa. ljb@sun.ac.za., van Wyk LM, Munro OQ, Barbour LJ |
| Jazyk: |
angličtina |
| Zdroj: |
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2018 Jun 21; Vol. 54 (51), pp. 6975-6978. |
| DOI: |
10.1039/c8cc02197j |
| Abstrakt: |
A solvatochromic dinuclear copper(ii) metallocycle effectively traps tetrahydrofuran, diethyl ether and pentane significantly above their boiling points. X-ray crystallography, EPR and UV-visible spectroscopy were used to delineate an empirical relationship between the guest-induced structural perturbation of the metallocycle, the ligand field splitting parameter Δ (νmax), and the EPR g-values of the inclusion compounds, thereby elucidating the solvatochromic mechanism. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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