Acetylenic Cyclophanes as Fullerene Precursors: Formation of C 60 H 6 and C 60 by Laser Desorption Mass Spectrometry of C 60 H 6 (CO) 12 .

Autor: Rubin Y; Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095-1569 (USA), Fax: (+1) 310-206-7649., Parker TC; Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095-1569 (USA), Fax: (+1) 310-206-7649., Pastor SJ; Department of Chemistry, University of California, Riverside, Riverside, CA 92521 (USA), Fax: (+1) 909-787-4713., Jalisatgi S; Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095-1569 (USA), Fax: (+1) 310-206-7649., Boulle C; Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095-1569 (USA), Fax: (+1) 310-206-7649., Wilkins CL; Department of Chemistry, University of California, Riverside, Riverside, CA 92521 (USA), Fax: (+1) 909-787-4713.
Jazyk: angličtina
Zdroj: Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 1998 May 18; Vol. 37 (9), pp. 1226-1229.
DOI: 10.1002/(SICI)1521-3773(19980518)37:9<1226::AID-ANIE1226>3.0.CO;2-H
Abstrakt: A logical precursor of macrocycle C 60 H 6 , cyclophane C 60 H 6 (CO) 12 (1) represents a building block in a possible total synthesis of C 60 . In Fourier transform ion cyclotron resonance laser desorption mass spectroscopic experiments in the negative-ion mode, 1 fragments to C 60 H 6 (2) under successive loss of CO. Further loss of six H atoms and rearrangement gives C 60 ions with a fullerenic structure.
(© 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.)
Databáze: MEDLINE
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