Iron(MCP) Complexes Catalyze Aziridination with Olefins As Limiting Reagents.

Autor:	Shehata MF; Duke University , Department of Chemistry , Box 90346, Durham , North Carolina 27708-0354 , United States., Ayer SK; Duke University , Department of Chemistry , Box 90346, Durham , North Carolina 27708-0354 , United States., Roizen JL; Duke University , Department of Chemistry , Box 90346, Durham , North Carolina 27708-0354 , United States.
Jazyk:	angličtina
Zdroj:	The Journal of organic chemistry [J Org Chem] 2018 May 04; Vol. 83 (9), pp. 5072-5081. Date of Electronic Publication: 2018 Apr 25.
DOI:	10.1021/acs.joc.8b00402
Abstrakt:	Herein described are the first efficient nitrogen-atom transfer reactions mediated by iron N, N'-dimethyl- N, N'-bis(2-pyridinylmethyl)cyclohexane-1,2-diamine- (MCP-) and 2-({1-[(pyridin-2-ylmethyl)pyrrolidin-2-yl]pyrrolidin-1-yl}methyl)pyridine-type (PDP-type) complexes. These catalysts affect styrene aziridination under mild conditions based on a limiting quantity of olefin substrate.
Databáze:	MEDLINE
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