Carbene Transfer Reactions Catalysed by Dyes of the Metalloporphyrin Group.

Autor: Simões MMQ; Department of Chemistry & Organic Chemistry, Natural Products and Food Stuffs Unit (QOPNA), University of Aveiro, 3810-193 Aveiro, Portugal. msimoes@ua.pt., Gonzaga DTG; Departamento de Química Orgânica, Universidade Federal Fluminense, Niterói 24020-150, RJ, Brazil. danieltadeugonzaga@yahoo.com.br., Cardoso MFC; Departamento de Química Orgânica, Universidade Federal Fluminense, Niterói 24020-150, RJ, Brazil. marianafcc83@hotmail.com., Forezi LDSM; Departamento de Química Orgânica, Universidade Federal Fluminense, Niterói 24020-150, RJ, Brazil. ana.peixoto@ua.pt., Gomes ATPC; Department of Chemistry & Organic Chemistry, Natural Products and Food Stuffs Unit (QOPNA), University of Aveiro, 3810-193 Aveiro, Portugal. gneves@ua.pt., da Silva FC; Departamento de Química Orgânica, Universidade Federal Fluminense, Niterói 24020-150, RJ, Brazil. gqofernando@vm.uff.br., Ferreira VF; Departamento de Tecnologia Farmacêutica Química, Universidade Federal Fluminense, Niterói 24241-002, RJ, Brazil. vitorferreira@id.uff.br., Neves MGPMS; Department of Chemistry & Organic Chemistry, Natural Products and Food Stuffs Unit (QOPNA), University of Aveiro, 3810-193 Aveiro, Portugal., Cavaleiro JAS; Department of Chemistry & Organic Chemistry, Natural Products and Food Stuffs Unit (QOPNA), University of Aveiro, 3810-193 Aveiro, Portugal. jcavaleiro@ua.pt.
Jazyk: angličtina
Zdroj: Molecules (Basel, Switzerland) [Molecules] 2018 Mar 29; Vol. 23 (4). Date of Electronic Publication: 2018 Mar 29.
DOI: 10.3390/molecules23040792
Abstrakt: Carbene transfer reactions are very important transformations in organic synthesis, allowing the generation of structurally challenging products by catalysed cyclopropanation, cyclopropenation, carbene C-H, N-H, O-H, S-H, and Si-H insertion, and olefination of carbonyl compounds. In particular, chiral and achiral metalloporphyrins have been successfully explored as biomimetic catalysts for these carbene transfer reactions under both homogeneous and heterogeneous conditions. In this work the use of synthetic metalloporphyrins (MPorph, M = Fe, Ru, Os, Co, Rh, Ir, Sn) as homogeneous or heterogeneous catalysts for carbene transfer reactions in the last years is reviewed, almost exclusively focused on the literature since the year 2010, except when reference to older publications was deemed to be crucial.
Competing Interests: The authors declare no conflict of interest.
Databáze: MEDLINE
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