Electrophoretic Mechanism of Au 25 (SR) 18 Heating in Radiofrequency Fields.

Autor: Collins CB; Department of Chemistry , Colorado State University , 1847 Campus Delivery , Fort Collins , Colorado 80523 , United States., Tofanelli MA; Department of Chemistry , University of Pittsburgh , Pittsburgh , Pennsylvania 15260 , United States., Noblitt SD; CHD Bioscience 3185-A Rampart Road , Fort Collins , Colorado 80521 , United States., Ackerson CJ; Department of Chemistry , Colorado State University , 1847 Campus Delivery , Fort Collins , Colorado 80523 , United States.
Jazyk: angličtina
Zdroj: The journal of physical chemistry letters [J Phys Chem Lett] 2018 Apr 05; Vol. 9 (7), pp. 1516-1521. Date of Electronic Publication: 2018 Mar 12.
DOI: 10.1021/acs.jpclett.8b00327
Abstrakt: Gold nanoparticles in radiofrequency (RF) fields have been observed to heat. There is some debate over the mechanism of heating. Au 25 (SR) 18 in RF is studied for the mechanistic insights obtainable from precise synthetic control over exact charge, size, and spin for this nanoparticle. An electrophoretic mechanism can adequately account for the observed heat. This study adds a new level of understanding to gold particle heating experiments, allowing for the first time a conclusive connection between theoretical and experimentally observed heating rates.
Databáze: MEDLINE
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