Engineered Transport in Microporous Materials and Membranes for Clean Energy Technologies.

Autor:	Li C; Department of Chemical and Biomolecular Engineering, The University of California, Berkeley, CA, 94720, USA., Meckler SM; Department of Chemistry, The University of California, Berkeley, CA, 94720, USA., Smith ZP; Department of Chemical Engineering, The Massachusetts Institute of Technology, Cambridge, MA, 02139, USA., Bachman JE; Department of Chemical and Biomolecular Engineering, The University of California, Berkeley, CA, 94720, USA., Maserati L; Materials Sciences Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Rd, Berkeley, CA, 94720, USA., Long JR; Department of Chemical and Biomolecular Engineering, The University of California, Berkeley, CA, 94720, USA.; Department of Chemistry, The University of California, Berkeley, CA, 94720, USA.; Materials Sciences Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Rd, Berkeley, CA, 94720, USA., Helms BA; Materials Sciences Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Rd, Berkeley, CA, 94720, USA.; The Molecular Foundry, Lawrence Berkeley National Laboratory, 1 Cyclotron Rd, Berkeley, CA, 94720, USA.
Jazyk:	angličtina
Zdroj:	Advanced materials (Deerfield Beach, Fla.) [Adv Mater] 2018 Feb; Vol. 30 (8). Date of Electronic Publication: 2018 Jan 08.
DOI:	10.1002/adma.201704953
Abstrakt:	Many forward-looking clean-energy technologies hinge on the development of scalable and efficient membrane-based separations. Ongoing investment in the basic research of microporous materials is beginning to pay dividends in membrane technology maturation. Specifically, improvements in membrane selectivity, permeability, and durability are being leveraged for more efficient carbon capture, desalination, and energy storage, and the market adoption of membranes in those areas appears to be on the horizon. Herein, an overview of the microporous materials chemistry driving advanced membrane development, the clean-energy separations employing them, and the theoretical underpinnings tying membrane performance to membrane structure across multiple length scales is provided. The interplay of pore architecture and chemistry for a given set of analytes emerges as a critical design consideration dictating mass transport outcomes. Opportunities and outstanding challenges in the field are also discussed, including high-flux 2D molecular-sieving membranes, phase-change adsorbents as performance-enhancing components in composite membranes, and the need for quantitative metrologies for understanding mass transport in heterophasic materials and in micropores with unusual chemical interactions with analytes of interest. (© 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Databáze:	MEDLINE
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