Li 6 Na 3 Sr 14 Al 11 P 22 O 90 : an oxo-centered Al 3 cluster based phosphate constructed from two types of (3,6)-connected kgd layers.

Autor: Yao XN; Key Laboratory of Magnetic Molecules and Magnetic Information Material of Ministry of Education, School of Chemistry and Material Science, Shanxi Normal University, Linfen, 041004, China. yg_chen80@sina.com zhangxm@dns.sxnu.edu.cn., Chen YG, Guo Y, Jia YJ, Jiang XX, Zhang XM
Jazyk: angličtina
Zdroj: Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2018 Jan 02; Vol. 47 (2), pp. 298-301.
DOI: 10.1039/c7dt03854b
Abstrakt: A novel and thermally stable aluminum phosphate Li 6 Na 3 Sr 14 Al 11 P 22 O 90 (1) has been achieved by using a solid-state molten method, which contains an oxo-centered trinuclear cluster and an anti-Lowenstein's rule Al-O-Al linkage and is constructed from two types of (3,6)-connected kgd layers [Al(Al 3 O)(PO 4 ) 7 ] 25- and [Al(PO 4 ) 2 ] 3- . The good optical transparency in the whole UV range and excellent thermal stability make the title compound a potential optical window material.
Databáze: MEDLINE