| Autor: |
Cao H; Department of Nanotechnology, Institute of Materials Research, Helmholtz-Zentrum Geesthacht GmbH, Max-Planck-Straße 1, D-21502, Geesthacht, Germany. hujun.cao@hzg.de., Zhang W, Pistidda C, Puszkiel J, Milanese C, Santoru A, Karimi F, Castro Riglos MV, Gizer G, Welter E, Bednarcik J, Etter M, Chen P, Klassen T, Dornheim M |
| Jazyk: |
angličtina |
| Zdroj: |
Physical chemistry chemical physics : PCCP [Phys Chem Chem Phys] 2017 Dec 06; Vol. 19 (47), pp. 32105-32115. |
| DOI: |
10.1039/c7cp06826c |
| Abstrakt: |
The 6Mg(NH 2 ) 2 -9LiH-LiBH 4 composite system has a maximum reversible hydrogen content of 4.2 wt% and a predicted dehydrogenation temperature of about 64 °C at 1 bar of H 2 . However, the existence of severe kinetic barriers precludes the occurrence of de/re-hydrogenation processes at such a low temperature (H. Cao, G. Wu, Y. Zhang, Z. Xiong, J. Qiu and P. Chen, J. Mater. Chem. A, 2014, 2, 15816-15822). In this work, Li 3 N and YCl 3 have been chosen as co-additives for this system. These additives increase the hydrogen storage capacity and hasten the de/re-hydrogenation kinetics: a hydrogen uptake of 4.2 wt% of H 2 was achieved in only 8 min under isothermal conditions at 180 °C and 85 bar of H 2 pressure. The re-hydrogenation temperature, necessary for a complete absorption process, can be lowered below 90 °C by increasing the H 2 pressure above 185 bar. Moreover, the results indicate that the hydrogenation capacity and absorption kinetics can be maintained roughly constant over several cycles. Low operating temperatures, together with fast absorption kinetics and good reversibility, make this system a promising on-board hydrogen storage material. The reasons for the improved de/re-hydrogenation properties are thoroughly investigated and discussed. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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