Autor: |
Won WS; Department of Chemistry & Chemical Biology, Rutgers The State University of New Jersey., Knapp S; Department of Chemistry & Chemical Biology, Rutgers The State University of New Jersey. |
Jazyk: |
angličtina |
Zdroj: |
Journal of sulphur chemistry [J Sulphur Chem] 2013; Vol. 34 (1-2), pp. 33-37. Date of Electronic Publication: 2012 Aug 10. |
DOI: |
10.1080/17415993.2012.706814 |
Abstrakt: |
A short synthetic route to β,d-arabinofuranosyl 1-C-sulfonic acid ( 7 ), a possible biomimetic for the arabinofuranosyl anomeric phosphate, is described. The furanosyl 1- C -sulfonate was prepared by buffered DMDO oxidation of an S -acetyl-1-thio-β-arabinofuranose derivative. Deprotection under mild conditions allowed isolation of the free sulfonic acid without desulfonylation. |
Databáze: |
MEDLINE |
Externí odkaz: |
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