β-D-Arabinosyl 1-C-sulfonic acid .

Autor: Won WS; Department of Chemistry & Chemical Biology, Rutgers The State University of New Jersey., Knapp S; Department of Chemistry & Chemical Biology, Rutgers The State University of New Jersey.
Jazyk: angličtina
Zdroj: Journal of sulphur chemistry [J Sulphur Chem] 2013; Vol. 34 (1-2), pp. 33-37. Date of Electronic Publication: 2012 Aug 10.
DOI: 10.1080/17415993.2012.706814
Abstrakt: A short synthetic route to β,d-arabinofuranosyl 1-C-sulfonic acid ( 7 ), a possible biomimetic for the arabinofuranosyl anomeric phosphate, is described. The furanosyl 1- C -sulfonate was prepared by buffered DMDO oxidation of an S -acetyl-1-thio-β-arabinofuranose derivative. Deprotection under mild conditions allowed isolation of the free sulfonic acid without desulfonylation.
Databáze: MEDLINE
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