| Autor: |
Erickson KA; Chemistry Division, Los Alamos National Laboratory, Mail Stop J514, Los Alamos, NM 87545, USA. kiplinger@lanl.gov., Kagan BD, Scott BL, Morris DE, Kiplinger JL |
| Jazyk: |
angličtina |
| Zdroj: |
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2017 Aug 29; Vol. 46 (34), pp. 11208-11213. |
| DOI: |
10.1039/c7dt02373a |
| Abstrakt: |
The reaction of (C 5 Me 5 ) 2 AnCl 2 (An = Th, U) with 2.8 or 4 equivalents of LiNMe 2 , respectively, affords (C 5 Me 5 ) 2 An(NMe 2 ) 2 in high yields. In addition to improved syntheses, the solid-state structures, voltammetric data, and UV-visible-NIR spectra for these classic actinide bis(dimethylamido) complexes are presented for the first time. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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