Crystal structure of (1 E ,1' E )-1,1'-(pyridine-2,6-di-yl)bis-[ N -(2,3,4,5,6-penta-fluoro-phen-yl)ethan-1-imine].

Autor: Boyle J; Department of Chemistry and Physics, Saint Mary's College, Notre Dame, IN 46556, USA., Breakfield C; Department of Chemistry and Physics, Saint Mary's College, Notre Dame, IN 46556, USA., Buck L; Department of Chemistry and Physics, Saint Mary's College, Notre Dame, IN 46556, USA., McMahon C; Department of Chemistry and Physics, Saint Mary's College, Notre Dame, IN 46556, USA., Babbini DC; Department of Chemistry and Physics, Saint Mary's College, Notre Dame, IN 46556, USA.
Jazyk: angličtina
Zdroj: Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2017 Jun 02; Vol. 73 (Pt 7), pp. 954-956. Date of Electronic Publication: 2017 Jun 02 (Print Publication: 2017).
DOI: 10.1107/S2056989017008040
Abstrakt: The title compound, C 21 H 9 F 10 N 3 , represents a potential redox non-innocent pyridine di-imine ligand system. It consists of a central pyridine ring with two penta-fluoro-phenyl substituted imine groups in positions 2 and 6. The whole mol-ecule is generated by mirror symmetry, the mirror bis-ecting the N and para -C atom of the pyridine ring. The perfluoro-phenyl ring is inclined to the pyridine ring by 73.67 (8)°. In the crystal, mol-ecules stack along the a axis, but there are no significant inter-molecular inter-actions present.
Databáze: MEDLINE