Autor: |
Boyle J; Department of Chemistry and Physics, Saint Mary's College, Notre Dame, IN 46556, USA., Breakfield C; Department of Chemistry and Physics, Saint Mary's College, Notre Dame, IN 46556, USA., Buck L; Department of Chemistry and Physics, Saint Mary's College, Notre Dame, IN 46556, USA., McMahon C; Department of Chemistry and Physics, Saint Mary's College, Notre Dame, IN 46556, USA., Babbini DC; Department of Chemistry and Physics, Saint Mary's College, Notre Dame, IN 46556, USA. |
Abstrakt: |
The title compound, C 21 H 9 F 10 N 3 , represents a potential redox non-innocent pyridine di-imine ligand system. It consists of a central pyridine ring with two penta-fluoro-phenyl substituted imine groups in positions 2 and 6. The whole mol-ecule is generated by mirror symmetry, the mirror bis-ecting the N and para -C atom of the pyridine ring. The perfluoro-phenyl ring is inclined to the pyridine ring by 73.67 (8)°. In the crystal, mol-ecules stack along the a axis, but there are no significant inter-molecular inter-actions present. |