| Autor: |
Valyaev DA; LCC-CNRS, Université de Toulouse, INPT, UPS, 205 route de Narbonne 31077, Toulouse Cedex 4, France. dmitry.valyaev@lcc-toulouse.fr noel.lugan@lcc-toulouse.fr., Willot J, Mangin LP, Zargarian D, Lugan N |
| Jazyk: |
angličtina |
| Zdroj: |
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2017 Aug 08; Vol. 46 (31), pp. 10193-10196. |
| DOI: |
10.1039/c7dt02190a |
| Abstrakt: |
The alkylation of N-(2-pyridyl)imidazole by the Mn I methylene-phosphonium complex [Cp(CO) 2 Mn(η 2 -P,C-Ph 2 P[double bond, length as m-dash]C(H)Ph)]BF 4 offers a straightforward route to a tridentate pro-ligand featuring an NHC core and phosphine/pyridine arms. The ability of this PĈN ligand to coordinate in a pincer mode was recognized in Rh I , Rh III , and Ni II complexes. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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