| Autor: |
Sekino M; Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan. h-furutachi@se.kanazawa-u.ac.jp., Furutachi H, Tojo R, Hishi A, Kajikawa H, Suzuki T, Suzuki K, Fujinami S, Akine S, Sakata Y, Ohta T, Hayami S, Suzuki M |
| Jazyk: |
angličtina |
| Zdroj: |
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2017 Aug 03; Vol. 53 (63), pp. 8838-8841. |
| DOI: |
10.1039/c7cc04382a |
| Abstrakt: |
A (μ-peroxo)diiron(iii) complex [Fe 2 (L Ph 4 )(O 2 )(Ph 3 CCO 2 )] 2+ (1-O 2 ) with a dinucleating ligand (L Ph 4 ), generated from the reaction of a carboxylate bridged diiron(ii) complex [Fe 2 (L Ph 4 )(Ph 3 CCO 2 )] 2+ (1) with dioxygen in CH 2 Cl 2 , provides a diiron(iv)-oxo species as an active oxidant which is involved in either aromatic ligand hydroxylation or benzyl alcohol oxidation. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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