| Autor: |
Ben-Daat H; School of Molecular Sciences, Arizona State University, Tempe, Arizona 85287, USA. ryan.trovitch@asu.edu., Rock CL, Flores M, Groy TL, Bowman AC, Trovitch RJ |
| Jazyk: |
angličtina |
| Zdroj: |
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2017 Jun 29; Vol. 53 (53), pp. 7333-7336. |
| DOI: |
10.1039/c7cc02281f |
| Abstrakt: |
Addition of NaEt 3 BH to ( Ph2PPr DI)CoCl 2 affords the corresponding monohydride, ( Ph2PPr DI)CoH. X-ray diffraction and DFT calculations indicate that this compound possesses a radical monoanion α-DI chelate and a Co(ii) centre. Notably, ( Ph2PPr DI)CoH catalyzes the hydroboration of alkynes and dihydroboration of nitriles under mild conditions. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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