Isoxazole derivatives as new nitric oxide elicitors in plants.

Autor: Oancea A; National Institute of Research and Development for Biological Sciences, Spl. Independentei 296, RO-060031 Bucharest, Romania., Georgescu E; Research Center Oltchim, Str. Uzinei 1, RO-240050, Ramnicu Valcea, Romania., Georgescu F; Research Dept., Teso Spec SRL, Str. Muncii 53, RO-915200 Fundulea, Calarasi, Romania., Nicolescu A; Petru Poni Institute of Macromolecular Chemistry, Romanian Academy, Aleea Grigore Ghica Voda 41-A, RO-700487 Iasi, Romania.; C. D. Nenitescu Centre of Organic Chemistry, Romanian Academy, Spl. Independentei 202-B, RO-060023 Bucharest, Romania., Oprita EI; National Institute of Research and Development for Biological Sciences, Spl. Independentei 296, RO-060031 Bucharest, Romania., Tudora C; National Institute of Research and Development for Biological Sciences, Spl. Independentei 296, RO-060031 Bucharest, Romania., Vladulescu L; Research Dept., Teso Spec SRL, Str. Muncii 53, RO-915200 Fundulea, Calarasi, Romania., Vladulescu MC; Research Dept., Teso Spec SRL, Str. Muncii 53, RO-915200 Fundulea, Calarasi, Romania., Oancea F; National Research & Development Institute for Chemistry & Petrochemistry - ICECHIM, Spl. Independentei 202, RO-060021 Bucharest, Romania., Deleanu C; Petru Poni Institute of Macromolecular Chemistry, Romanian Academy, Aleea Grigore Ghica Voda 41-A, RO-700487 Iasi, Romania.; C. D. Nenitescu Centre of Organic Chemistry, Romanian Academy, Spl. Independentei 202-B, RO-060023 Bucharest, Romania.
Jazyk: angličtina
Zdroj: Beilstein journal of organic chemistry [Beilstein J Org Chem] 2017 Apr 06; Vol. 13, pp. 659-664. Date of Electronic Publication: 2017 Apr 06 (Print Publication: 2017).
DOI: 10.3762/bjoc.13.65
Abstrakt: Several 3,5-disubstituted isoxazoles were obtained in good yields by regiospecific 1,3-dipolar cycloaddition reactions between aromatic nitrile oxides, generated in situ from the corresponding hydroxyimidoyl chlorides, with non-symmetrical activated alkynes in the presence of catalytic amounts of copper(I) iodide. Effects of 3,5-disubstituted isoxazoles on nitric oxide and reactive oxygen species generation in Arabidopsis tissues was studied using specific diaminofluoresceine dyes as fluorescence indicators.
Databáze: MEDLINE