| Autor: |
Plasch K; Department of Chemistry, Organic & Bioorganic Chemistry University of Graz Heinrichstrasse 28A-8010 Graz Austria., Resch V; Department of Chemistry, Organic & Bioorganic Chemistry University of Graz Heinrichstrasse 28A-8010 Graz Austria., Hitce J; L'Oréal Research & Innovation 30 bis rue Maurice Berteaux 95500 Le Thillay France., Popłoński J; Department of Chemistry Wrocław University of Environmental and Life Sciences ul. C. K. Norwida 2550-375 Wrocław Poland., Faber K; Department of Chemistry, Organic & Bioorganic Chemistry University of Graz Heinrichstrasse 28A-8010 Graz Austria., Glueck SM; Department of Chemistry, Organic & Bioorganic Chemistry University of Graz Heinrichstrasse 28A-8010 Graz Austria.; Austrian Centre of Industrial Biotechnology (ACIB) University of Graz Heinrichstrasse 28A-8010 Graz Austria. |
| Jazyk: |
angličtina |
| Zdroj: |
Advanced synthesis & catalysis [Adv Synth Catal] 2017 Mar 20; Vol. 359 (6), pp. 959-965. Date of Electronic Publication: 2017 Jan 18. |
| DOI: |
10.1002/adsc.201601046 |
| Abstrakt: |
In order to extend the applicability of the regioselective enzymatic carboxylation of phenols, the substrate scope of o -benzoic acid (de)carboxylases has been investigated towards complex molecules with an emphasis on flavouring agents and polyphenols possessing antioxidant properties. o -Hydroxycarboxylic acid products were obtained with perfect regioselectivity, in moderate to excellent yields. The applicability of this method was proven by the regioselective bio-carboxylation of resveratrol on a preparative scale with 95% yield. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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