| Autor: |
Liu W; Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Ministry-of-Education Key Laboratory for Synthesis and Applications of Organic Functional Molecules, Hubei University , Wuhan 430062, China., Zhou T; Institute for Superconducting and Electronic Materials, School of Mechanical, Materials, and Mechatronics Engineering, University of Wollongong , North Wollongong, NSW 2500, Australia., Zheng Y; Institute for Superconducting and Electronic Materials, School of Mechanical, Materials, and Mechatronics Engineering, University of Wollongong , North Wollongong, NSW 2500, Australia., Liu J; Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Ministry-of-Education Key Laboratory for Synthesis and Applications of Organic Functional Molecules, Hubei University , Wuhan 430062, China., Feng C; Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Ministry-of-Education Key Laboratory for Synthesis and Applications of Organic Functional Molecules, Hubei University , Wuhan 430062, China., Shen Y; State Key Laboratory of Material Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology , Wuhan, Hubei 430074, China., Huang Y; State Key Laboratory of Material Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology , Wuhan, Hubei 430074, China., Guo Z; Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Ministry-of-Education Key Laboratory for Synthesis and Applications of Organic Functional Molecules, Hubei University , Wuhan 430062, China.; Institute for Superconducting and Electronic Materials, School of Mechanical, Materials, and Mechatronics Engineering, University of Wollongong , North Wollongong, NSW 2500, Australia. |
| Abstrakt: |
Zinc germinate (Zn 2 GeO 4 ) with a hierarchical structure was successfully synthesized in a binary ethylenediamine/water (En/H 2 O) solvent system by wet chemistry methods. The morphological evolution process of the Zn 2 GeO 4 was investigated in detail by tuning the ratio of En to H 2 O in different solvent systems, and a series of compounds with awl-shaped, fascicular, and cross-linked hierarchical structures was obtained and employed as anode materials in lithium-ion batteries. The materials with fascicular structure exhibited excellent electrochemical performance, and a specific reversible capacity of 1034 mA h g -1 was retained at a current density of 0.5 A g -1 after 160 cycles. In addition, the as-prepared nanostructured electrode also delivered impressive rate capability of 315 mA h g -1 at the current density of 10 A g -1 . The remarkable electrochemical performances could be ascribed to the following aspects. First, each unit in the three-dimensional fascicular structure can effectively buffer the volume expansions during the Li + extraction/insertion process, accommodate the strain induced by the volume variation, and stabilize its whole configuration. Meanwhile, the small fascicular units can enlarge the electrode/electrolyte contact area and form an integrated interlaced conductive network which provides continuous electron/ion pathways. |
