A Cryptand Metal-Organic Framework as a Platform for the Selective Uptake and Detection of Group I Metal Cations.

Autor: Sapchenko SA; Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Acad. Lavrentiev Ave., Novosibirsk, 630090, Russian Federation.; Department of Natural Sciences, Novosibirsk State University, 2 Pirogova Str., Novosibirsk, 630090, Russian Federation., Demakov PA; Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Acad. Lavrentiev Ave., Novosibirsk, 630090, Russian Federation.; Department of Natural Sciences, Novosibirsk State University, 2 Pirogova Str., Novosibirsk, 630090, Russian Federation., Samsonenko DG; Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Acad. Lavrentiev Ave., Novosibirsk, 630090, Russian Federation.; Department of Natural Sciences, Novosibirsk State University, 2 Pirogova Str., Novosibirsk, 630090, Russian Federation., Dybtsev DN; Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Acad. Lavrentiev Ave., Novosibirsk, 630090, Russian Federation.; Department of Natural Sciences, Novosibirsk State University, 2 Pirogova Str., Novosibirsk, 630090, Russian Federation., Schröder M; Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Acad. Lavrentiev Ave., Novosibirsk, 630090, Russian Federation.; School of Chemistry, University of Manchester, Manchester, M13 9PL, UK., Fedin VP; Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Acad. Lavrentiev Ave., Novosibirsk, 630090, Russian Federation.; Department of Natural Sciences, Novosibirsk State University, 2 Pirogova Str., Novosibirsk, 630090, Russian Federation.
Jazyk: angličtina
Zdroj: Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2017 Feb 16; Vol. 23 (10), pp. 2286-2289. Date of Electronic Publication: 2017 Jan 20.
DOI: 10.1002/chem.201605895
Abstrakt: The metal-organic framework (MOF) complex (H 3 O) 2 [Zn 4 (ur)(Hfdc) 2 (fdc) 4 ] (1, ur=urotropine, H 2 fdc=furan-2,5-dicarboxylic acid) incorporates cryptand-like cavities, which can be used to separate and detect Rb + and Cs + optically. This is the first example of the effective employment of a MOF material for optical detection of these cations.
(© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Databáze: MEDLINE
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