Chemical Variability of Ivoirian Xylopia rubescens Leaf Oil.

Autor: Yapi TA; UMR 6134 SPE, Equipe Chimie et Biomasse, Université de Corse-CNRS, Route des Sanguinaires, FR-20000, Ajaccio.; Laboratoire de Chimie Organique Biologique, UFR-SSMT, Université Félix Houphouët-Boigny, BPV 34, Abidjan, Côte d'Ivoire., Boti JB; Laboratoire de Chimie Organique Biologique, UFR-SSMT, Université Félix Houphouët-Boigny, BPV 34, Abidjan, Côte d'Ivoire., Tonzibo ZF; Laboratoire de Chimie Organique Biologique, UFR-SSMT, Université Félix Houphouët-Boigny, BPV 34, Abidjan, Côte d'Ivoire., Ahibo CA; Laboratoire de Chimie Organique Biologique, UFR-SSMT, Université Félix Houphouët-Boigny, BPV 34, Abidjan, Côte d'Ivoire., Bighelli A; UMR 6134 SPE, Equipe Chimie et Biomasse, Université de Corse-CNRS, Route des Sanguinaires, FR-20000, Ajaccio., Casanova J; UMR 6134 SPE, Equipe Chimie et Biomasse, Université de Corse-CNRS, Route des Sanguinaires, FR-20000, Ajaccio., Tomi F; UMR 6134 SPE, Equipe Chimie et Biomasse, Université de Corse-CNRS, Route des Sanguinaires, FR-20000, Ajaccio.
Jazyk: angličtina
Zdroj: Chemistry & biodiversity [Chem Biodivers] 2017 Feb; Vol. 14 (2).
DOI: 10.1002/cbdv.201600200
Abstrakt: Forty-two essential oil samples were isolated from leaves of Xylopia rubescens harvested in three forests of Southern Ivory Coast. All the samples have been submitted to GC-FID and the retention indices (RIs) of individual components have been measured on two capillary columns of different polarity. In addition, 20 oil samples, selected on the basis of their chromatographic profile, were also analyzed by 13 C-NMR and 24 components (78.0 - 92.4% of the whole compositions) have been identified. The content of the main components varied drastically from sample to sample: furanoguaia-1,4-diene (5.7 - 54.1%), furanoguaia-1,3-diene (1.1 - 10.5%), (8Z,11Z,14Z)-heptadeca-8,11,14-trien-2-one (4.3 - 16.0%), and (E)-β-caryophyllene (1.7 - 17.3%). Hierarchical cluster and principal components analysis of the 42 oil compositions allowed the distinction of two well-differentiated groups of unequal importance within the oil samples. Oil samples of the main group (Group II) contained mainly furanoguaia-1,4-diene (mean [M] = 43.1%; standard deviation [SD] = 3.2%) while furanoguaia-1,3-diene (M = 8.4%; SD = 0.9%) and (8Z,11Z,14Z)-heptadeca-8,11,14-trien-2-one (M = 7.1%; SD = 1.5%) were present at appreciable contents. The composition of Group I was dominated by furanoguaia-1,4-diene (M = 17.0%; SD = 8.5%), (8Z,11Z,14Z)-heptadeca-8,11,14-trien-2-one (M = 10.2%; SD = 2.4%) and (E)-β-caryophyllene (M = 9.5%; SD = 5.3%).
(© 2017 Wiley-VHCA AG, Zurich, Switzerland.)
Databáze: MEDLINE
Externí odkaz: