| Autor: |
Andrews NL; Department of Chemistry, Queen's University, Kingston, ON K7L 3N6, Canada. hploock@queensu.ca., Fan JZ; Department of Chemistry, Queen's University, Kingston, ON K7L 3N6, Canada. hploock@queensu.ca., Forward RL; Department of Chemistry, Queen's University, Kingston, ON K7L 3N6, Canada. hploock@queensu.ca., Chen MC; Department of Chemistry, Queen's University, Kingston, ON K7L 3N6, Canada. hploock@queensu.ca., Loock HP; Department of Chemistry, Queen's University, Kingston, ON K7L 3N6, Canada. hploock@queensu.ca. |
| Abstrakt: |
The thermal, oxidative and photochemical stability of the scintillator liquid proposed for the SNO+ experiment has been tested experimentally using accelerated aging methods. The stability of the scintillator constituents was determined through fluorescence excitation emission matrix (EEM) spectroscopy and absorption spectroscopy, using parallel factor analysis (PARAFAC) as an multivariate analysis tool. By exposing the scintillator liquid to a well-known photon flux at 365 nm and by measuring the decay rate of the fluorescence shifters and the formation rate of their photochemical degradation products, we can place an upper limit on the acceptable photon flux as 1.38 ± 0.09 × 10 -11 photon mol L -1 . Similarly, the oxidative stability of the scintillator liquid was determined by exposure to air at several elevated temperatures. Through measurement of the corresponding activation energy it was determined that the average oxygen concentration would have to be kept below 4.3-7.1 ppb w (headspace partial pressure below 24 ppm v ). On the other hand, the thermal stability of the scintillator cocktail in the absence of light and oxygen was remarkable and poses no concern to the SNO+ experiment. |
