Luminescent rare-earth-based MOFs as optical sensors.

Autor: Mahata P; Department of Chemistry, Suri Vidyasagar College, Suri, Birbhum, PIN-731101, West Bengal, India. parthachem@gmail.com., Mondal SK; Department of Chemistry, Siksha-Bhavana, Visva-Bharati University, Santiniketan-731235, West Bengal, India. sudip.mondal@visva-bharati.ac.in., Singha DK; Department of Chemistry, Suri Vidyasagar College, Suri, Birbhum, PIN-731101, West Bengal, India. parthachem@gmail.com., Majee P; Department of Chemistry, Siksha-Bhavana, Visva-Bharati University, Santiniketan-731235, West Bengal, India. sudip.mondal@visva-bharati.ac.in.
Jazyk: angličtina
Zdroj: Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2017 Jan 03; Vol. 46 (2), pp. 301-328.
DOI: 10.1039/c6dt03419e
Abstrakt: Rare-earth-based metal-organic frameworks (ReMOFs) have emerged as an interesting family of compounds, for which new properties are increasingly being found. Based on the potential of ReMOFs, resulting from their optical properties, large numbers of investigations have been carried out during the last decade. Among these investigations, ReMOFs as optical sensors, using their luminescence properties, are increasingly becoming an attractive and useful topic of research. In this study, we have provided the basics of the luminescence behaviour of ReMOFs, various possible sensing mechanisms, and a summary of the uses of ReMOFs for the sensing of nitro explosives, cations, anions, small molecules, pH, and temperature.
Databáze: MEDLINE