Chiral nanoscale pores created during the surface explosion of tartaric acid on Cu(111).

Autor:	Therrien AJ; Department of Chemistry, Tufts University, 62 Talbot Ave., Medford, MA 02155, USA. charles.sykes@tufts.edu., Lawton TJ; Department of Chemistry, Tufts University, 62 Talbot Ave., Medford, MA 02155, USA. charles.sykes@tufts.edu., Mernoff B; Department of Chemistry, Tufts University, 62 Talbot Ave., Medford, MA 02155, USA. charles.sykes@tufts.edu., Lucci FR; Department of Chemistry, Tufts University, 62 Talbot Ave., Medford, MA 02155, USA. charles.sykes@tufts.edu., Pushkarev VV; Department of Chemical Engineering, Carnegie Mellon University, Pittsburgh, PA 15213, USA., Gellman AJ; Department of Chemical Engineering, Carnegie Mellon University, Pittsburgh, PA 15213, USA and W.E. Scott Institute for Energy Innovation, Carnegie Mellon University, Pittsburgh, PA 15213, USA., Sykes EC; Department of Chemistry, Tufts University, 62 Talbot Ave., Medford, MA 02155, USA. charles.sykes@tufts.edu.
Jazyk:	angličtina
Zdroj:	Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2016 Dec 06; Vol. 52 (99), pp. 14282-14285.
DOI:	10.1039/c6cc05820e
Abstrakt:	The autocatalytic decomposition of tartaric acid on Cu(111) exhibits unique kinetics, which are linked to a hexagonal surface structure adopted at high coverage. The chirality imposed on the surface by tartaric acid throughout the explosion process is presented, and the hexagonal structure shows promise as a chiral template for enantiospecific surface chemistry.
Databáze:	MEDLINE
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