Direct synthesis of CdSe nanocrystals within a conducting metallopolymer: toward improving charge transfer in hybrid nanomaterials.

Autor: Nguyen MT; Department of Chemistry, The University of Texas at Austin, 105 E. 24th St., Mailstop A5300, Austin, TX 78712-1224, USA. minhnguyen@utexas.edu rajones@cm.utexas.edu hollidaybj@hotmail.com., Jones RA, Holliday BJ
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2016 Nov 18; Vol. 52 (89), pp. 13112-13115. Date of Electronic Publication: 2016 Oct 19.
DOI: 10.1039/c6cc07193g
Abstrakt: CdSe nanocrystals with tunable sizes and distributions were synthesized directly from Cd(ii) ions coordinated to the conjugated backbone of a thiophene-based conducting metallopolymer. Using our seeded growth technique, the resulting nanocrystals are in direct electronic communication with the polymer, which leads to effective charge transfer between the donor and acceptor.
Databáze: MEDLINE