The influence of phthalocyanine aggregation in complexes with CdSe/ZnS quantum dots on the photophysical properties of the complexes.

Autor: Martynenko IV; Department of optical physics and modern natural science, ITMO University, 197101 Saint Petersburg, Russia., Orlova AO; Department of optical physics and modern natural science, ITMO University, 197101 Saint Petersburg, Russia., Maslov VG; Department of optical physics and modern natural science, ITMO University, 197101 Saint Petersburg, Russia., Fedorov AV; Department of optical physics and modern natural science, ITMO University, 197101 Saint Petersburg, Russia., Berwick K; Department of Electronic and Communications Engineering, Dublin Institute of Technology, Dublin 8, Ireland., Baranov AV; Department of optical physics and modern natural science, ITMO University, 197101 Saint Petersburg, Russia.
Jazyk: angličtina
Zdroj: Beilstein journal of nanotechnology [Beilstein J Nanotechnol] 2016 Jul 13; Vol. 7, pp. 1018-27. Date of Electronic Publication: 2016 Jul 13 (Print Publication: 2016).
DOI: 10.3762/bjnano.7.94
Abstrakt: The formation of nonluminescent aggregates of aluminium sulfonated phthalocyanine in complexes with CdSe/ZnS quantum dots causes a decrease of the intracomplex energy transfer efficiency with increasing phthalocyanine concentration. This was confirmed by steady-state absorption and photoluminescent spectroscopy. A corresponding physical model was developed that describes well the experimental data. The results can be used at designing of QD/molecule systems with the desired spatial arrangement for photodynamic therapy.
Databáze: MEDLINE