| Autor: |
Han JL; Tianjin University, School of Chemical Engineering and Technology, Tianjin 300072, China. Youj1983@tju.edu.cn., You J, Yonemura H, Yamada S, Wang SR, Li XG |
| Jazyk: |
angličtina |
| Zdroj: |
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology [Photochem Photobiol Sci] 2016 Aug 04; Vol. 15 (8), pp. 1039-45. Date of Electronic Publication: 2016 Jul 19. |
| DOI: |
10.1039/c6pp00172f |
| Abstrakt: |
Soluble palladium and platinum phthalocyanines with coumarin moieties were synthesized with Q bands in the red and near-IR regions, in which the molar extinction coefficients were up to 1.01 × 10(5) cm(-1) mol(-1). These metallophthalocyanines were coupled with rubrene and applied in photon upconversion systems based on triplet-triplet annihilation. The highest upconversion efficiency of the palladium phthalocyanine was 5.6%, which is higher than that of the platinum phthalocyanine-rubrene system. The larger molar extinction coefficient resulted in high upconversion capability (>10(5) cm(-1) mol(-1)) and low saturation incident power (<20 mW cm(-2)). |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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