| Autor: |
Ibragimov AB; Institute of General and Inorganic Chemistry of Uzbekistan Academy of Sciences, M. Ulugbek Str. 77a, Tashkent 700170, Uzbekistan., Zakirov BS; Institute of General and Inorganic Chemistry of Uzbekistan Academy of Sciences, M. Ulugbek Str. 77a, Tashkent 700170, Uzbekistan., Ashurov JM; Institute of Bioorganic Chemistry Academy of Sciences of Uzbekistan, M. Ulugbek Str. 83, Tashkent 700125, Uzbekistan. |
| Jazyk: |
angličtina |
| Zdroj: |
Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2016 Mar 15; Vol. 72 (Pt 4), pp. 502-4. Date of Electronic Publication: 2016 Mar 15 (Print Publication: 2016). |
| DOI: |
10.1107/S2056989016004072 |
| Abstrakt: |
Reaction of m-amino-benzoic acid (MABA), di-ethano-lamine (DEA) and MnCl2·4H2O led to the formation of the title salt, [Mn(C4H11NO2)2](C7H6NO2)2. In the complex cation, the Mn(2+) ion is located on an inversion centre and is coordinated by two symmetry-related tridentate DEA mol-ecules, leading to the formation of a slightly distorted MnN2O4 octa-hedron. The MABA(-) counter-anions are connected to the complex ion by a pair of rather strong O-H⋯O hydrogen bonds, yielding a 1:2 supra-molecular aggregate. Much weaker N-H⋯O hydrogen bonds connect neighbouring aggregates into a three-dimensional network structure. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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