'Active Surfaces' as Possible Functional Systems in Detection and Chemical (Bio) Reactivity.

Autor: Housecroft CE; Department of Chemistry, University of Basel, Spitalstrasse 51, CH-4056 Basel, Switzerland. catherine.housecroft@unibas.ch., Palivan CG; Department of Chemistry, University of Basel, Klingelbergstrasse 80, CH-4056 Basel, Switzerland., Gademann K; Department of Chemistry, University of Zurich, Winterthurerstrasse 190, CH-8057 Zurich, Switzerland., Meier W; Department of Chemistry, University of Basel, Klingelbergstrasse 80, CH-4056 Basel, Switzerland., Calame M; Department of Physics, University of Basel, Klingelbergstrasse 82, CH-4056 Basel, Switzerland; Swiss Nanoscience Institute, University of Basel Klingelbergstrasse 82, CH-4056 Basel, Switzerland., Mikhalevich V; Department of Chemistry, University of Basel, Klingelbergstrasse 80, CH-4056 Basel, Switzerland., Zhang X; Department of Chemistry, University of Basel, Klingelbergstrasse 80, CH-4056 Basel, Switzerland., Piel E; Department of Chemistry, University of Zurich, Winterthurerstrasse 190, CH-8057 Zurich, Switzerland., Szponarski M; Department of Chemistry, University of Zurich, Winterthurerstrasse 190, CH-8057 Zurich, Switzerland., Wiesler A; Department of Chemistry, University of Basel, Spitalstrasse 51, CH-4056 Basel, Switzerland., Lanzilotto A; Department of Chemistry, University of Basel, Spitalstrasse 51, CH-4056 Basel, Switzerland., Constable EC; Department of Chemistry, University of Basel, Spitalstrasse 51, CH-4056 Basel, Switzerland., Fanget A; Department of Physics, University of Basel, Klingelbergstrasse 82, CH-4056 Basel, Switzerland., Stoop RL; Department of Physics, University of Basel, Klingelbergstrasse 82, CH-4056 Basel, Switzerland.
Jazyk: angličtina
Zdroj: Chimia [Chimia (Aarau)] 2016; Vol. 70 (6), pp. 402-12.
DOI: 10.2533/chimia.2016.402
Abstrakt: This article presents design strategies to demonstrate approaches to generate functionalized surfaces which have the potential for application in molecular systems; sensing and chemical reactivity applications are exemplified. Some applications are proven, while others are still under active investigation. Adaptation and extension of our strategies will lead to interfacing of different type of surfaces, specific interactions at a molecular level, and possible exchange of signals/cargoes between them. Optimization of the present approaches from each of five research groups within the NCCR will be directed towards expanding the types of functional surfaces and the properties that they exhibit.
Databáze: MEDLINE