| Autor: |
Hänninen MM; School of Chemistry, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK. Richard.Layfield@manchester.ac.uk., Pal K, Day BM, Pugh T, Layfield RA |
| Jazyk: |
angličtina |
| Zdroj: |
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2016 Jul 28; Vol. 45 (28), pp. 11301-5. Date of Electronic Publication: 2016 Jun 30. |
| DOI: |
10.1039/c6dt02486f |
| Abstrakt: |
The structural and bonding properties of a three-coordinate N-heterocyclic silyene (NHSi) complex of the iron(ii) amide [Fe{N(SiMe3)2}2] are reported. Computational studies reveal that dispersion forces between the amido SiMe3 substituents and the isopropyl substituents on the NHSi ligand significantly enhance the stability of the complex, along with Fe-to-Si π-backbonding. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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