Vibrational dynamics (IR, Raman, NRVS) and a DFT study of a new antitumor tetranuclearstannoxane cluster, Sn(iv)-oxo-{di-o-vanillin} dimethyl dichloride.

Autor: Arjmand F; Department of Chemistry, Aligarh Muslim University, Aligarh 202002, India. farukh_arjmand@yahoo.co.in., Sharma S, Usman M, Leu BM, Hu MY, Toupet L, Gosztola D, Tabassum S
Jazyk: angličtina
Zdroj: Physical chemistry chemical physics : PCCP [Phys Chem Chem Phys] 2016 Jul 21; Vol. 18 (27), pp. 17805-9. Date of Electronic Publication: 2016 Jun 21.
DOI: 10.1039/c6cp02914k
Abstrakt: The vibrational dynamics of a newly synthesized tetrastannoxane was characterized with a combination of experimental (Raman, IR and tin-based nuclear resonance vibrational spectroscopy) and computational (DFT/B3LYP) methods, with an emphasis on the vibrations of the tin sites. The cytotoxic activity revealed a significant regression selectively against the human pancreatic cell lines.
Databáze: MEDLINE