Crystal structure and spectroscopic analysis of a new oxalate-bridged Mn(II) compound: catena-poly[guanidinium [[aqua-chlorido-manganese(II)]-μ2-oxalato-κ(4) O (1),O (2):O (1'),O (2')] monohydrate].
| Autor: | Sehimi H; Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis El Manar, 2092 Manar II Tunis, Tunisia; Université de Gabès, Faculté des Sciences de Gabès, Campus Universitaire, Cité Erriadh Zrig, Gabès, 6072, Tunisia., Chérif I; Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis El Manar, 2092 Manar II Tunis, Tunisia; Université de Gabès, Faculté des Sciences de Gabès, Campus Universitaire, Cité Erriadh Zrig, Gabès, 6072, Tunisia., Zid MF; Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis El Manar, 2092 Manar II Tunis, Tunisia. |
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| Jazyk: | angličtina |
| Zdroj: | Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2016 Apr 26; Vol. 72 (Pt 5), pp. 724-9. Date of Electronic Publication: 2016 Apr 26 (Print Publication: 2016). |
| DOI: | 10.1107/S2056989016006605 |
| Abstrakt: | As part of our studies on the synthesis and the characterization of oxalate-bridged compounds M-ox-M (ox = oxalate dianion and M = transition metal ion), we report the crystal structure of a new oxalate-bridged Mn(II) phase, {(CH6N3)[Mn(C2O4)Cl(H2O)]·H2O} n . In the compound, a succession of Mn(II) ions (situated on inversion centers) adopting a distorted octa-hedral coordination and bridged by oxalate ligands forms parallel zigzag chains running along the c axis. These chains are inter-connected through O-H⋯O hydrogen-bonding inter-actions to form anionic layers parallel to (010). Individual layers are held together via strong hydrogen bonds involving the guanidinium cations (N-H⋯O and N-H⋯Cl) and the disordered non-coordinating water mol-ecule (O-H⋯O and O-H⋯Cl), as well as by guanidinium π-π stacking. The structural data were confirmed by IR and UV-Visible spectroscopic analysis. |
| Databáze: | MEDLINE |
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