The application of inelastic neutron scattering to investigate the interaction of methyl propanoate with silica.

Autor:	McFarlane AR; School of Chemistry, Joseph Black Building, University of Glasgow, Glasgow, G12 8QQ, UK. David.Lennon@glasgow.ac.uk., Geller H; School of Chemistry, Joseph Black Building, University of Glasgow, Glasgow, G12 8QQ, UK. David.Lennon@glasgow.ac.uk., Silverwood IP; School of Chemistry, Joseph Black Building, University of Glasgow, Glasgow, G12 8QQ, UK. David.Lennon@glasgow.ac.uk., Cooper RI; Chemical Crystallography, Chemistry Research Laboratory, Mansfield Road, Oxford OX1 3TA, UK., Watkin DJ; Chemical Crystallography, Chemistry Research Laboratory, Mansfield Road, Oxford OX1 3TA, UK., Parker SF; ISIS Facility, STFC Rutherford Appleton Laboratory, Chilton, Didcot, Oxon OX11 0QX, UK., Winfield JM; School of Chemistry, Joseph Black Building, University of Glasgow, Glasgow, G12 8QQ, UK. David.Lennon@glasgow.ac.uk., Lennon D; School of Chemistry, Joseph Black Building, University of Glasgow, Glasgow, G12 8QQ, UK. David.Lennon@glasgow.ac.uk.
Jazyk:	angličtina
Zdroj:	Physical chemistry chemical physics : PCCP [Phys Chem Chem Phys] 2016 Jun 29; Vol. 18 (26), pp. 17210-6.
DOI:	10.1039/c6cp01276k
Abstrakt:	A modern industrial route for the manufacture of methyl methacrylate involves the reaction of methyl propanoate and formaldehyde over a silica-supported Cs catalyst. Although the process has been successfully commercialised, little is known about the surface interactions responsible for the forward chemistry. This work concentrates upon the interaction of methyl propanoate over a representative silica. A combination of infrared spectroscopy, inelastic neutron scattering, DFT calculations, X-ray diffraction and temperature-programmed desorption is used to deduce how the ester interacts with the silica surface.
Databáze:	MEDLINE
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