Phenyliodonium Diacetate Mediated Oxidative Functionalization of Styrenes with Molecular Oxygen: Synthesis of α-Oxygenated Ketones.
| Autor: | Samanta S; Academy of Scientific & Innovative Research, CSIR-Central Salt & Marine Chemicals Research Institute , G.B. Marg, Bhavnagar 364 002. Gujarat, India., Donthiri RR; Academy of Scientific & Innovative Research, CSIR-Central Salt & Marine Chemicals Research Institute , G.B. Marg, Bhavnagar 364 002. Gujarat, India., Ravi C; Academy of Scientific & Innovative Research, CSIR-Central Salt & Marine Chemicals Research Institute , G.B. Marg, Bhavnagar 364 002. Gujarat, India., Adimurthy S; Academy of Scientific & Innovative Research, CSIR-Central Salt & Marine Chemicals Research Institute , G.B. Marg, Bhavnagar 364 002. Gujarat, India. |
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| Jazyk: | angličtina |
| Zdroj: | The Journal of organic chemistry [J Org Chem] 2016 Apr 15; Vol. 81 (8), pp. 3457-63. Date of Electronic Publication: 2016 Apr 06. |
| DOI: | 10.1021/acs.joc.6b00266 |
| Abstrakt: | Synthesis of α-oxygenated ketones from styrenes mediated by phenyliodonium diacetate in the presence of molecular oxygen and N-hydroxyphthalimide or N-hydroxybenzotriazole has been described. Addition of carbonyl oxygen at the α-position and formation of C-O bond at the β-position of styrenes was achieved under metal-free conditions. The present method is applicable for wide range of styrenes with a variety of functional groups. |
| Databáze: | MEDLINE |
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