Crystal structure of fac-tricarbon-yl(cyclo-hexyl isocyanide-κC)(quinoline-2-carboxyl-ato-κ(2) N,O)rhenium(I).

Autor: Triantis C; Institute of Nuclear and Radiological Sciences and Technology, Energy and Safety, National Centre for Scientific Research 'Demokritos', 15310 Athens, Greece., Shegani A; Institute of Nuclear and Radiological Sciences and Technology, Energy and Safety, National Centre for Scientific Research 'Demokritos', 15310 Athens, Greece., Kiritsis C; Institute of Nuclear and Radiological Sciences and Technology, Energy and Safety, National Centre for Scientific Research 'Demokritos', 15310 Athens, Greece., Raptopoulou C; Institute of Nanoscience and Nanotechnology, National Centre for Scientific Research 'Demokritos', 15310 Athens, Greece., Psycharis V; Institute of Nanoscience and Nanotechnology, National Centre for Scientific Research 'Demokritos', 15310 Athens, Greece., Pelecanou M; Institute of Biosciences & Applications, National Centre for Scientific Research 'Demokritos', 15310 Athens, Greece., Pirmettis I; Institute of Nuclear and Radiological Sciences and Technology, Energy and Safety, National Centre for Scientific Research 'Demokritos', 15310 Athens, Greece., Papadopoulos M; Institute of Nuclear and Radiological Sciences and Technology, Energy and Safety, National Centre for Scientific Research 'Demokritos', 15310 Athens, Greece.
Jazyk: angličtina
Zdroj: Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2016 Feb 17; Vol. 72 (Pt 3), pp. 358-62. Date of Electronic Publication: 2016 Feb 17 (Print Publication: 2016).
DOI: 10.1107/S2056989016002206
Abstrakt: In the title compound, [Re(C10H6NO2)(C7H11N)(CO)3], the Re(I) atom is coordinated by three carbonyl ligands in a facial arrangement and by the N, O and C atoms from a chelating quinaldate anion and a monodentate isocyanide ligand, respectively. The resultant C4NO coordination sphere is distorted octa-hedral. A lengthening of the axial Re-CO bond trans to the isocyanide ligand is indicative of the trans effect. Individual complexes are stacked into rods parallel to [001] through displaced π-π inter-actions. Weak C-H⋯O hydrogen-bonding inter-actions between the rods lead to the formation of layers parallel to (010). These layers are stacked along [010] by C-H⋯H-C van der Waals contacts.
Databáze: MEDLINE
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