Crystal structure of 1,1'-[selanediyl-bis(4,1-phenyl-ene)]bis-(2-chloro-ethan-1-one).

Autor: Bouraoui H; Laboratoire de Cristallographie, Département de Physique, Université Mentouri-Constantine, 25000 Constantine, Algeria., Boudjada A; Laboratoire de Cristallographie, Département de Physique, Université Mentouri-Constantine, 25000 Constantine, Algeria., Hamdouni N; Laboratoire de Cristallographie, Département de Physique, Université Mentouri-Constantine, 25000 Constantine, Algeria., Mechehoud Y; Laboratoire VAREN, Département de chimie, Faculté des Sciences Exactes, Université Mentouri-Constantine, 25000 Constantine, Algeria., Meinnel J; UMR 6226 CNRS-Université Rennes 1 'Sciences Chimiques de Rennes', Equipe 'Matière Condensée et Systèmes Electroactifs', 263 Avenue du Général Leclerc, F-35042 Rennes, France.
Jazyk: angličtina
Zdroj: Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2015 Nov 14; Vol. 71 (Pt 12), pp. o935-6. Date of Electronic Publication: 2015 Nov 14 (Print Publication: 2015).
DOI: 10.1107/S2056989015019969
Abstrakt: In the title mol-ecule, C16H12Cl2O2Se, the C-Se-C angle is 100.05 (14)°, with the dihedral angle between the planes of the benzene rings being 69.92 (17)°. The average endocyclic angles (Se-Car-Car; ar = aromatic) facing the Se atom are 120.0 (3) and 119.4 (3)°. The Se atom is essentially coplanar with the benzene rings, with Se-Car-Car-Car torsion angles of -179.2 (3) and -179.7 (3)°. In the crystal, mol-ecules are linked via C-H⋯O hydrogen bonds forming chains propagating along the a-axis direction. The chains are linked via C-H⋯π inter-actions, forming a three-dimensional network.
Databáze: MEDLINE