Crystal structure of ethyl 5-[3-(di-methyl-amino)-acrylo-yl]-2-{[(di-methyl-amino)-methyl-idene]-amino}-4-methylthio-phene-3-carb-oxy-late.

Autor: Krishnamurthy MS; Department of Studies in Chemistry, Central College Campus, Bangalore University, Bangalore 560 001, Karnataka, India., Prasad NL; Department of Studies in Chemistry, Central College Campus, Bangalore University, Bangalore 560 001, Karnataka, India., Nagarajaiah H; Department of Studies in Chemistry, Central College Campus, Bangalore University, Bangalore 560 001, Karnataka, India., Begum NS; Department of Studies in Chemistry, Central College Campus, Bangalore University, Bangalore 560 001, Karnataka, India.
Jazyk: angličtina
Zdroj: Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2015 Nov 04; Vol. 71 (Pt 12), pp. o908-9. Date of Electronic Publication: 2015 Nov 04 (Print Publication: 2015).
DOI: 10.1107/S2056989015018885
Abstrakt: In the title compound, C16H23N3O3S, the dihedral angles between the thio-phene ring and the almost planar di-methyl-amino-methyl-ene-amino (r.m.s. deviation = 0.005 Å) and di-methyl-amino-acryloyl (r.m.s. deviation = 0.033 Å) substituents are 6.99 (8) and 6.69 (7)°, respectively. The ester CO2 group subtends a dihedral angle of 44.92 (18)° with the thio-phene ring. An intra-molecular C-H⋯O hydrogen bond generates an S(6) ring. In the crystal, inversion dimers linked by pairs of C-H⋯O hydrogen bonds generate R (2) 2(14) loops. In addition, a weak C-H⋯π inter-action is observed.
Databáze: MEDLINE