Introducing Dimensionality to the Archetypical Mn12 Single-Molecule Magnet: a Family of [Mn12]n Chains.

Autor: Corrales SA; Department of Chemistry, University of North Florida , 1 UNF Drive, Jacksonville, Florida 32224, United States., Cain JM; Department of Chemistry, University of North Florida , 1 UNF Drive, Jacksonville, Florida 32224, United States., Uhlig KA; Department of Chemistry, University of North Florida , 1 UNF Drive, Jacksonville, Florida 32224, United States., Mowson AM; Department of Chemistry, University of Florida , Gainesville, Florida 32611-7200, United States., Papatriantafyllopoulou C; Department of Chemistry, University of Cyprus , 1678 Nicosia, Cyprus., Peprah MK; Department of Physics and National High Magnetic Field Laboratory (NHMFL), University of Florida , Gainesville, Florida 32611-8440, United States., Ozarowski A; National High Magnetic Field Laboratory (NHMFL), Florida State University , Tallahassee, Florida 32310, United States., Tasiopoulos AJ; Department of Chemistry, University of Cyprus , 1678 Nicosia, Cyprus., Christou G; Department of Chemistry, University of Florida , Gainesville, Florida 32611-7200, United States., Meisel MW; Department of Physics and National High Magnetic Field Laboratory (NHMFL), University of Florida , Gainesville, Florida 32611-8440, United States., Lampropoulos C; Department of Chemistry, University of North Florida , 1 UNF Drive, Jacksonville, Florida 32224, United States.
Jazyk: angličtina
Zdroj: Inorganic chemistry [Inorg Chem] 2016 Feb 15; Vol. 55 (4), pp. 1367-9. Date of Electronic Publication: 2016 Feb 04.
DOI: 10.1021/acs.inorgchem.6b00058
Abstrakt: The [Mn12O12(O2CR)16(L4)] family (R = various; L = terminal ligand) of clusters holds a special place in molecular magnetism; they are the most well-studied single-molecule magnets (SMMs). Targeted linkage of these SMMs has now been achieved for the first time. The resulting chain structures have been confirmed crystallographically, and the magnetic properties, up to 1.14 GPa, and high-field electron paramagnetic resonance spectra have been collected and analyzed.
Databáze: MEDLINE