Tunable functionalization of graphene nanosheets for graphene-organic hybrid photodetectors.

Autor: Kim SJ; Thin Film Materials Research Center, Korea Research Institute of Chemical Technology, Daejeon 305-600, Korea. Nanomaterials Science and Engineering, University of Science and Technology, Daejeon 305-350, Korea., Song W, Kim S, Kang MA, Myung S, Sook Lee S, Lim J, An KS
Jazyk: angličtina
Zdroj: Nanotechnology [Nanotechnology] 2016 Feb 19; Vol. 27 (7), pp. 075709. Date of Electronic Publication: 2016 Jan 20.
DOI: 10.1088/0957-4484/27/7/075709
Abstrakt: Graphene-organic hybrid thin films are promising candidates for use as advanced transparent electrodes and high-performance photodetectors. In this work, we fabricated hybrid thin film structures consisting of graphene and either tetraphenyl-porphyrin (H2TPP) or metalloporphyrins such as aluminum (III) tetraphenyl-porphyrin (Al(III)TPP) and zinc tetraphenyl-porphyrin (ZnTPP). The optical and electrical characteristics of ultrathin photodetectors based on the graphene-organic hybrid layers were subsequently evaluated. A hybrid deposition system capable of both thermal evaporation and vapor phase metalation was employed to synthesize the tunable metalloporphyrin-based thin films. As a proof of concept, we successfully fabricated various graphene-based photodetectors via the simple and efficient vapor-phase metalation of porphyrin. This work may facilitate the development of new architectures for flexible graphene-organic devices.
Databáze: MEDLINE