Rearrangement of N-benzyl-2-cyano-2-(hydroxyimino)acetamide.
| Autor: | Darling CM, Chen CP |
|---|---|
| Jazyk: | angličtina |
| Zdroj: | Journal of pharmaceutical sciences [J Pharm Sci] 1978 Jun; Vol. 67 (6), pp. 860-1. |
| DOI: | 10.1002/jps.2600670636 |
| Abstrakt: | The reduction of N-benzyl-2-cyano-2-(hydroxyimino)acetamide resulted in the formation of N-benzyl-1,2-ethanediamine and N-benzyl-N'-methyl-1,2-ethanediamine in approximately an equimolar ratio. The formation of the two unexpected products is explained by the migration of a cyano group in a Beckmann-type rearrangement. |
| Databáze: | MEDLINE |
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