Development of a Steel-Slag-Based, Iron-Functionalized Sorbent for an Autothermal Carbon Dioxide Capture Process.

Autor: Tian S; School of Environment, Tsinghua University, 100084, Beijing, P.R. China., Jiang J; School of Environment, Tsinghua University, 100084, Beijing, P.R. China. jianguoj@tsinghua.edu.cn.; Key Laboratory for Solid Waste Management and Environment Safety, Ministry of Education of China, Tsinghua University, 100084, Beijing, P.R. China. jianguoj@tsinghua.edu.cn.; Collaborative Innovation Center for Regional Environmental Quality, Tsinghua University, 100084, Beijing, P.R. China. jianguoj@tsinghua.edu.cn., Hosseini D; Laboratory of Energy Science and Engineering, Department of Mechanical and Process Engineering, ETH Zürich, Leonhardstrasse 21, 8092, Zürich, Switzerland., Kierzkowska AM; Laboratory of Energy Science and Engineering, Department of Mechanical and Process Engineering, ETH Zürich, Leonhardstrasse 21, 8092, Zürich, Switzerland., Imtiaz Q; Laboratory of Energy Science and Engineering, Department of Mechanical and Process Engineering, ETH Zürich, Leonhardstrasse 21, 8092, Zürich, Switzerland., Broda M; Laboratory of Energy Science and Engineering, Department of Mechanical and Process Engineering, ETH Zürich, Leonhardstrasse 21, 8092, Zürich, Switzerland., Müller CR; Laboratory of Energy Science and Engineering, Department of Mechanical and Process Engineering, ETH Zürich, Leonhardstrasse 21, 8092, Zürich, Switzerland.
Jazyk: angličtina
Zdroj: ChemSusChem [ChemSusChem] 2015 Nov; Vol. 8 (22), pp. 3839-46. Date of Electronic Publication: 2015 Oct 13.
DOI: 10.1002/cssc.201501048
Abstrakt: We propose a new class of autothermal CO2 -capture process that relies on the integration of chemical looping combustion (CLC) into calcium looping (CaL). In the new process, the heat released during the oxidation of a reduced metallic oxide is utilized to drive the endothermic calcination of CaCO3 (the regeneration step in CaL). Such a process is potentially very attractive (both economically and technically) as it can be applied to a variety of oxygen carriers and CaO is not in direct contact with coal (and the impurities associated with it) in the calciner (regeneration step). To demonstrate the practical feasibility of the process, we developed a low-cost, steel-slag-based, Fe-functionalized CO2 sorbent. Using this material, we confirm experimentally the feasibility to heat-integrate CaCO3 calcination with a Fe(II)/Fe(III) redox cycle (with regards to the heat of reaction and kinetics). The autothermal calcination of CaCO3 could be achieved for a material that contained a Ca/Fe ratio of 5:4. The uniform distribution of Ca and Fe in a solid matrix provides excellent heat transfer characteristics. The cyclic CO2 uptake and redox stability of the material is good, but there is room for further improvement.
(© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Databáze: MEDLINE
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