Cyclization of Pyrene Oligomers: Cyclohexa-1,3-pyrenylene.

Autor: Lorbach D; Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz (Germany)., Keerthi A; Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz (Germany)., Figueira-Duarte TM; Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz (Germany)., Baumgarten M; Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz (Germany)., Wagner M; Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz (Germany)., Müllen K; Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz (Germany). muellen@mpip-mainz.mpg.de.
Jazyk: angličtina
Zdroj: Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2016 Jan 04; Vol. 55 (1), pp. 418-21. Date of Electronic Publication: 2015 Nov 06.
DOI: 10.1002/anie.201508180
Abstrakt: First synthesis of the macrocycle cyclohexa(1,3-pyrenylene) is achieved in six steps starting with pyrene, leading to a non-aggregating highly twisted blue-light-emitting material. The cyclodehydrogenation of the macrocycle offers a promising synthesis route to holey-nanographene.
(© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Databáze: MEDLINE
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