Lanthanide luminescent logic gate mimics in soft matter: [H(+)] and [F(-)] dual-input device in a polymer gel with potential for selective component release.

Autor: Bradberry SJ; School of Chemistry and Trinity Biomedical Sciences Institute (TBSI), Trinity College Dublin, 152 - 160 Pearse Street, Dublin 2, Ireland. gunnlaut@tcd.ie bradbers@tcd.ie., Byrne JP; School of Chemistry and Trinity Biomedical Sciences Institute (TBSI), Trinity College Dublin, 152 - 160 Pearse Street, Dublin 2, Ireland. gunnlaut@tcd.ie bradbers@tcd.ie., McCoy CP; School of Pharmacy, Queen's University Belfast, Belfast, BT9 7BL, UK., Gunnlaugsson T; School of Chemistry and Trinity Biomedical Sciences Institute (TBSI), Trinity College Dublin, 152 - 160 Pearse Street, Dublin 2, Ireland. gunnlaut@tcd.ie bradbers@tcd.ie.
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2015 Nov 28; Vol. 51 (92), pp. 16565-8.
DOI: 10.1039/c5cc05009j
Abstrakt: The non-covalent incorporation of responsive luminescent lanthanide, Ln(III), complexes with orthogonal outputs from Eu(III) and Tb(III) in a gel matrix allows for in situ logic operation with colorimetric outputs. Herein, we report an exemplar system with two inputs ([H(+)] and [F(-)]) within a p(HEMA-co-MMA) polymer organogel acting as a dual-responsive device and identify future potential for such systems.
Databáze: MEDLINE