| Autor: |
Santoro O; EaStCHEM School of Chemistry, University of St Andrews, St Andrews, KY16 9ST, UK. cc111@st-andrews.ac.uk., Lazreg F, Minenkov Y, Cavallo L, Cazin CS |
| Jazyk: |
angličtina |
| Zdroj: |
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2015 Nov 07; Vol. 44 (41), pp. 18138-44. Date of Electronic Publication: 2015 Sep 30. |
| DOI: |
10.1039/c5dt03506f |
| Abstrakt: |
The N-methylation of amines using CO2 and PhSiH3 as source of CH3 was efficiently performed using a N-heterocyclic carbene copper(i) complex. The methodology was found compatible with aromatic and aliphatic primary and secondary amines. Synthetic and computational studies have been carried out to support the proposed reaction mechanism for this transformation. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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