| Autor: |
Wrixon JD; Department of Chemistry and Biochemistry, University of Windsor , 401 Sunset Avenue, Windsor, Ontario N9B3P4, Canada., Hayward JJ; Department of Chemistry and Biochemistry, University of Windsor , 401 Sunset Avenue, Windsor, Ontario N9B3P4, Canada., Rawson JM; Department of Chemistry and Biochemistry, University of Windsor , 401 Sunset Avenue, Windsor, Ontario N9B3P4, Canada. |
| Jazyk: |
angličtina |
| Zdroj: |
Inorganic chemistry [Inorg Chem] 2015 Oct 05; Vol. 54 (19), pp. 9384-6. Date of Electronic Publication: 2015 Sep 15. |
| DOI: |
10.1021/acs.inorgchem.5b01555 |
| Abstrakt: |
The outcome of the oxidative addition reactions of bis(4',5'-dimethoxybenzo)-1,2,5,6-tetrathiocin to Pd2dba3 under microwave conditions is sensitive to the nature of the phosphine coreagent; the bidentate phosphines dppm, dppe, and dppf afford the mononuclear dithiolates (dmobdt)Pd(dppm) (4), (dmobdt)Pd(dppe) (2), and (dmobdt)Pd(dppf) (5), whereas more labile monodentate phosphines lead to aggregation; Ph3P afforded the dinuclear dithiolate (dmobdt)2Pd2(PPh3)2 (6), whereas (t)Bu3P generated the phosphine-free hexanuclear edge-capped octahedral complex Pd6(dmobdt)6 (7) [dmobdt = 4,5-dimethoxybenzenedithiolate, (MeO)2C6H2S2(2-)]. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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