Preparation of a porphyrinic bis(pyridyl aldehyde) and its supramolecular complexes.

Autor: Greaves CR; Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, UK. nb10013@cam.ac.uk., Alemán García MÁ, Bampos N
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2015 Nov 07; Vol. 51 (86), pp. 15689-91.
DOI: 10.1039/c5cc06399j
Abstrakt: Shape-specific molecular assemblies require the preparation of the constituent building blocks with the necessary properties to bias exclusive formation of the proposed structures. In this work, a novel linear porphyrin dialdehyde was synthesised and used to assemble a supramolecular grid via Cu(i) heteroleptic phenanthroline/pyridyl imine complexation, and a tetrahedral cage via Fe(ii) pyridyl imine coordination.
Databáze: MEDLINE