Autor: |
Greaves CR; Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, UK. nb10013@cam.ac.uk., Alemán García MÁ, Bampos N |
Jazyk: |
angličtina |
Zdroj: |
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2015 Nov 07; Vol. 51 (86), pp. 15689-91. |
DOI: |
10.1039/c5cc06399j |
Abstrakt: |
Shape-specific molecular assemblies require the preparation of the constituent building blocks with the necessary properties to bias exclusive formation of the proposed structures. In this work, a novel linear porphyrin dialdehyde was synthesised and used to assemble a supramolecular grid via Cu(i) heteroleptic phenanthroline/pyridyl imine complexation, and a tetrahedral cage via Fe(ii) pyridyl imine coordination. |
Databáze: |
MEDLINE |
Externí odkaz: |
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