Novel phenanthroline-diaryldiazadiene ligands with heteroditopic coordination spheres.

Autor: Sorsche D; Ulm University, Institute of Inorganic Chemistry I, Albert-Einstein-Allee 11, 89081 Ulm, Germany. sven.rau@uni-ulm.de., Pehlken C, Baur C, Rommel S, Kastner K, Streb C, Rau S
Jazyk: angličtina
Zdroj: Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2015 Sep 21; Vol. 44 (35), pp. 15404-7. Date of Electronic Publication: 2015 Aug 10.
DOI: 10.1039/c5dt02383a
Abstrakt: 1,10-Phenanthroline-5,6-diaryldiazadienes are key structures for the development of novel heterodinuclear photocatalysts and for the construction of extended heterocycles of potential biological use. Herein, the first examples of this compound family are presented together with a wide range of initial reactivity studies. Synthetic strategies are presented to access the two first derivatives of the ligand and to accomplish subsequent metal coordination to the phenanthroline sphere.
Databáze: MEDLINE