| Autor: |
Bispinghoff M; Laboratory of Inorganic Chemistry, ETH Zürich, Vladimir-Prelog-Weg 1, 8093 Zürich, Switzerland. hgruetzmacher@ethz.ch., Tondreau AM, Grützmacher H, Faradji CA, Pringle PG |
| Jazyk: |
angličtina |
| Zdroj: |
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2016 Apr 14; Vol. 45 (14), pp. 5999-6003. Date of Electronic Publication: 2015 Jun 30. |
| DOI: |
10.1039/c5dt01741f |
| Abstrakt: |
PH3 reacts with the in situ generated N-heterocyclic carbene DippNHC* (DippNHC* = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) to give the phosphanyl-imidazolidine [(Dipp)NHC*-H]-[PH2]. Upon treatment with an ortho-quinone, [(Dipp)NHC*-H]-[PH2] is dehydrogenated to give the parent phosphinidene-carbene adduct (Dipp)NHC*[double bond, length as m-dash]PH. Alternative routes to [(Dipp)NHC*-H]-[PH2] and (Dipp)NHC*[double bond, length as m-dash]PH employ NaPH2 and (TMS)3P7 (TMS = trimethylsilyl), respectively, as phosphorus sources. The adduct (Dipp)NHC*[double bond, length as m-dash]PH and the related adduct (Dipp)NHC[double bond, length as m-dash]PH ((Dipp)NHC = bis(2,6-diisopropylphenyl)imidazol-2-ylidene) possessing an unsaturated NHC backbone both react with HgCl2 to give the bis(carbene-phosphinidenyl) complexes [((Dipp)NHC*[double bond, length as m-dash]P)2Hg] and [((Dipp)NHC[double bond, length as m-dash]P)2Hg]. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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