Tailoring flavins for visible light photocatalysis: organocatalytic [2+2] cycloadditions mediated by a flavin derivative and visible light.

Autor: Mojr V; Department of Organic Chemistry, University of Chemistry and Technology, Prague, Technická 5, 166 28 Prague, Czech Republic. cibulkar@vscht.cz., Svobodová E, Straková K, Neveselý T, Chudoba J, Dvořáková H, Cibulka R
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2015 Aug 04; Vol. 51 (60), pp. 12036-9.
DOI: 10.1039/c5cc01344e
Abstrakt: A new application of flavin derivatives in visible light photocatalysis was found. 1-Butyl-7,8-dimethoxy-3-methylalloxazine, when irradiated by visible light, was shown to allow an efficient cyclobutane ring formation via an intramolecular [2+2] cycloaddition of both styrene dienes, considered as electron-rich substrates, and electron-poor bis(arylenones), presumably proceeding via an energy transfer mechanism.
Databáze: MEDLINE